京都大学 · 工学部・工学研究科 · 助教

研究关键词helical polymer catalysis・asymmetric catalysis・C H activation・borylation chemistry・iterative oligoarenes・Suzuki coupling

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• Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich ReactionJOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
• Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-MethylenecyclopropanesJOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
• Development of Dynamically Chiral Helical Polymer Catalysts Based on Post-Polymerization Modification of Boronyl PendantsJournal of Synthetic Organic Chemistry, Japan,
• PQXdpap: Helical Poly(quinoxaline-2,3-diyl)s Bearing 4-(Dipropylamino)pyridin-3-yl Pendants as Chirality-Switchable Nucleophilic Catalysts for the Kinetic Resolution of Secondary AlcoholsOrganic Letters,

• 光学活性ヘリセン誘導体の触媒的不斉合成と機能性材料への応用
• 高分子らせんダイナミクスの自在制御に基づいたキラル機能性材料の開拓
• アリールボロン酸とジアミンの重縮合反応に基づく新規光学活性らせん高分子の開発
• 不斉増幅を特徴とするキラルゲスト応答性らせん高分子触媒の創製

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