Kyoto University · Institute for Chemical Research

Research keywordsnitrogenase・iron sulfur clusters・metalloclusters・CO2 reduction・bioinorganic chemistry・small molecule activation・artificial enzymes・spectroscopic characterization

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• Non-centrosymmetric coordination polymer with a highly hindered octahedral copper center bridged by mandelate.Inorganic chemistry,
• Synthetic analogues of [Fe4S4(Cys)3(His)] in hydrogenases and [Fe4S4(Cys)4] in HiPIP derived from all-ferric [Fe4S4{N(SiMe3)2}4].Proceedings of the National Academy of Sciences of the United States of America,
• An EPR and VTVH MCD spectroscopic investigation of the nitrogenase assembly protein NifBJOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY,
• A convenient route to synthetic analogues of the oxidized form of high-potential iron-sulfur proteins.Inorganic chemistry,

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