Tokushima University · Faculty of Pharmaceutical Sciences · 准教授

Research keywordsorganic synthesis・asymmetric catalysis・bromolactonization・thiourea catalysis・hetero-Michael reaction・unnatural amino acids

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• Synthesis of optically active N-aryl amino acid derivatives through the asymmetric petasis reaction catalyzed by a novel hydroxy-thiourea catalyst
• Remote electronic effect on the N-heterocyclic carbene-catalyzed asymmetric intramolecular Stetter reaction and structural revision of products
• Stereoselective Synthesis of 3-Alkylideneoxindoles using Tandem Indium-Mediated Carbometallation and Palladium-Catalyzed Cross-Coupling Reactions
• Bronsted Acid-Thiourea Co-catalysis: Asymmetric Synthesis of Functionalized 1,4-Dihydropyridines from beta-Enamino Esters and alpha,beta-Unsaturated Aldehydes

• インドリルグリシン不斉構築を基盤とした新規非天然アミノ酸含有ペプチド合成法の開発
• アリールグリシン不斉構築と非天然アミノ酸含有ペプチド効率的合成への展開
• ホスホフロリダート化学で拓くキロベース DNA の自在合成
• 真に実用的なペプチド・タンパク質機能制御を可能とする刺激応答型アミノ酸の開発

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